PSV vs Napoli Correct Score Prediction: Team Stats, H2H & Betting Insights

Our PSV vs Napoli Prediction: 1-2

PSV vs Napoli in the UEFA Champions League is scheduled for an 19:00 GMT kick-off on Tuesday October 21, 2025. We anticipate a 1-2 away victory, but given both teams’ ability to score, BTTS seems like a valuable betting option.

This PSV vs Napoli prediction is backed by a deep dive into both teams' recent performances, key stats and head-to-head history — all of which you'll find detailed below to help you make an informed betting decision.

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Recent Form Insights

PSV's Last Match – PEC Zwolle vs PSV

PSV must win to build on their momentum after securing a hard-fought 4-0 Netherlands Eredivisie victory over PEC Zwolle in their last outing. In that match, PSV saw 72% of the ball and created 14 goal attempts, with 11 on target.

Team	Possession	Shots (on target)	xG	Dangerous Attacks
PEC Zwolle	28%	2 (0)	0.12	31
PSV	72%	14 (11)	1.85	101

Napoli's Last Match – Napoli vs Genoa

Napoli will aim to maintain their momentum following a 2-1 Italy Serie A triumph against Genoa on October 5. In that match, Napoli had 69% possession and 9 attempts at goal, with 5 on target.

Team	Possession	Shots (on target)	xG	Dangerous Attacks
Napoli	69%	9 (5)	1.1	57
Genoa	31%	4 (1)	0.44	26

PSV vs Napoli Stats

Key Stats

Goals Scored vs Goals Conceded

PSV are averaging 2.7 goals scored and 1.5 conceded per match, while Napoli average 2.0 scored and 1.0 conceded per game.

Napoli Fixtures