PSV vs Napoli Correct Score Prediction: Team Stats, H2H & Betting Insights

Our PSV vs Napoli Prediction: 1-2

PSV vs Napoli in the UEFA Champions League is scheduled for an 19:00 GMT kick-off on Tuesday October 21, 2025. We anticipate a 1-2 away victory, but given both teams’ ability to score, BTTS seems like a valuable betting option.

This PSV vs Napoli prediction is backed by a deep dive into both teams' recent performances, key stats and head-to-head history — all of which you'll find detailed below to help you make an informed betting decision.

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Recent Form Insights

PSV's Last Match – PSV vs Go Ahead Eagles

PSV must win to build on their momentum after securing a hard-fought 2-1 Netherlands Eredivisie victory over Go Ahead Eagles in their last outing. In that match, PSV saw 57% of the ball and created 17 goal attempts, with 7 on target.

Team	Possession	Shots (on target)	xG	Dangerous Attacks
PSV	57%	17 (7)	3.1	41
Go Ahead Eagles	43%	4 (2)	0.41	31

Napoli's Last Match – Torino vs Napoli

Napoli will aim to put their last result behind them following a 0-1 Italy Serie A loss to Torino on October 18. In that match, Napoli had 69% possession and 15 attempts at goal, with 5 on target.

Team	Possession	Shots (on target)	xG	Dangerous Attacks
Torino	31%	8 (2)	1.97	27
Napoli	69%	15 (5)	1.82	51

PSV vs Napoli Stats

Key Stats

Goals Scored vs Goals Conceded

PSV are averaging 2.3 goals scored and 1.5 conceded per match, while Napoli average 1.6 scored and 1.1 conceded per game.

PSV Fixtures

Napoli Fixtures